Network of Palladium-Based Nanorings Synthesized by Liquid-Phase Reduction Using DMSO-H2O : In Situ Monitoring of Structure Formation and Drying Deformation by ASEM

We developed a liquid-phase synthesis method for Pd-based nanostructure, in which Pd dissolved in dimethyl sulfoxide (DMSO) solutions was precipitated using acid aqueous solution. In the development of the method, in situ monitoring using atmospheric scanning electron microscopy (ASEM) revealed that three-dimensional (3D) Pd-based nanonetworks were deformed to micrometer-size particles possibly by the surface tension of the solutions during the drying process. To avoid surface tension, critical point drying was employed to dry the Pd-based precipitates. By combining ASEM monitoring with critical point drying, the synthesis parameters were optimized, resulting in the formation of lacelike delicate nanonetworks using citric acid aqueous solutions. Precipitation using HCl acid aqueous solutions allowed formation of 500-nm diameter nanorings connected by nanowires. The 3D nanostructure formation was controllable and modifiable into various shapes using different concentrations of the Pd and Cl ions as the parameters.

Media Type:

Electronic Article

Year of Publication:

2020

Contained In:

International journal of molecular sciences - Vol. 21, No. 9 (2020)

Language:

English

Contributors:

Komenami, Takuki
Yoshimura, Akihiro
Matsuno, Yasunari
Sato, Mari
Sato, Chikara

Urls:

Volltext

Keywords:

Atmospheric scanning electron microscopy
Critical point drying
Journal Article
Nanoparticles
Nanostructures
Precious metals

Notes:

Date Revised 11.06.2020

published: Electronic

Citation Status In-Process

Copyright: From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine

Physical Description:

Online-Ressource

doi:

10.3390/ijms21093271

PMID:

32380757

PPN (Catalogue-ID):

NLM310504767